Automated Solution-Phase Synthesis of β-1,4-Mannuronate and β-1,4-Mannan
نویسندگان
چکیده
منابع مشابه
Automated Solution-Phase Synthesis of β-1,4-Mannuronate and β-1,4-Mannan
The first automated solution-phase synthesis of β-1,4-mannuronate and β-1,4-mannan oligomers has been accomplished by using a β-directing C-5 carboxylate strategy. By utilizing fluorous-tag assisting purification after repeated reaction cycles, β-1,4-mannuronate was synthesized up to a hexasaccharide with limited loading of a glycosyl donor (up to 3.5 equiv) for each glycosylation cycle due to ...
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2015
ISSN: 1523-7060,1523-7052
DOI: 10.1021/acs.orglett.5b01013